Nickel(II), Cadmium(II), and Copper(II) Complexes Based on Ditopic Terpyridine Derivative Ligand: Syntheses, Crystal Structures, and Luminescent Properties

Abstract

AbstractThree complexes with the ditopic ligand 4′‐[4‐(quinolin‐8‐yloxymethyl)phenyl]‐2,2′:6′,2′′‐terpyridine (abbreviated as L), [Ni(L)2](CH3COO)2 (1), [Cd(L)2](ClO4)2 (2), and [Cu2(L)2](ClO4)4·4DMF (3), were synthesized and characterized by elemental analysis, IR spectroscopy, and structurally analyzed by X‐ray single‐crystal diffraction. Interestingly, in complexes 1 and 2, two ligands adopt a tridentate chelating pattern where the oxaquinoline group is non‐coordinated and coordinate with one MII ion (M = Ni for 1, M = Cd for 2) to form a mononuclear unit. In complex 3, two ligands bridge two CuII ions by pyridyl N atoms, ethereal O atoms, and quinolyl N atoms in a head‐to‐tail mode to generate a dinuclear [Cu2L2] unit. Moreover, extended 1D and 2D supramolecular architectures are further constructed in 1–3 by multiple secondary interactions such as aromatic stacking and hydrogen bonding. Notably, the structural diversity of complexes 1–3 can be properly assigned to the central metal ions that have distinct coordination preferences. In addition, luminescent properties of the ligand and complex 2 were also investigated.