Nickel–heterocumulene complexes stabilized by trimethylphosphine: Synthesis, characterization and catalytic application in organozinc coupling with CS2

Abstract

The reactivity of Ni(PMe3)4 with CO2, CS2 and SCNPh was studied. Although CO2 is structurally homologous compound with CS2 and SCNPh, its reactivity with Ni(PMe3)4 shows a different result with those of CS2 and SCNPh. Reactions of Ni(PMe3)4 with carbon disulfide and phenyl isothiocyanate in THF give the tetrahedral coordinate complexes (Me3P)3Ni(η2-CS2) (1) and (Me3P)3Ni(η2-SCNPh) (3), characterized by standard spectroscopic methods and X-ray diffraction. Nickel(0) complexes 1 and 3 are stabilized by the strong donor ligand PMe3. In the case of CO2, attempts to isolate the expected nickel(0) complex (Me3P)3Ni(η2-CO2) (4) proved to be unsuccessful. To further extend the utility of our nickel catalysts, the catalytic coupling of organozinc bearing different functionalities with CS2 was explored. With 10mol% of 1 as the catalyst, MeZnMe, EtZnEt and PhZnBr coupled with CS2 to form the corresponding methyl dithiocarboxylate following esterfication of the initial products.