Nickel-Electrocatalyzed Synthesis of Bifuran-Based Monomers.

Abstract

Bifuran motifs can be accessed with nickel-bipyridine electrocatalyzed homocouplings of bromine-substituted methyl furancarboxylates, which, in turn, can be prepared from hemicellulose-derived furfural. The described protocol uses sustainable carbon-based graphite electrodes in the simplest setup - an undivided cell with constant current electrolysis. The reported method avoids using a sacrificial anode by employing triethanolamine as an electron donor.