Nickel-containing nanophases as the carriers of catalytic active sites in the ethylene oligomerization in the presence of systems based on Ni(acac)2 and organoaluminum compounds

Abstract

The nature and size of particles, formed under conditions of the ethylene oligomerization in the systems based on nickel bis(acetylacetonate) with Et2AlCl or Et2AlCl·Cl2AlEt (Al: Ni = 50: 1), have been determined using ex situ HRTEM, electron diffraction and EDAX in combination with EPR spectroscopy and kinetic studies. It was revealed that the average sizes of Ni-containing particles depend on the nature of cocatalyst and are ∼3.5 and ∼6 nm for the systems derived from Et2AlCl and Et2AlCl·Cl2AlEt, respectively. It was shown that these nanoparticles act as the carriers of catalytically active sites during the C2H4 conversion.