Abstract

The syntheses of N-alkylated derivatives of the arenethiol 4-tert-butyl-2,6-(diaminomethyl)- thiophenol and their coordination properties are reported. Compounds 4-tert-butyl-2,6-di(N-isopropyl- aminomethyl)thiophenol (3) and 4-tert-butyl-2-(N-isopropyl-aminomethyl)-6-hydroxymethylthiophenol (6 ) react with Ni(II) salts to give compounds of composition [Ni(3)2]·2HCl (7) and [Ni(6)2] (8). The solid- and solution-state structures of both complexes consist of mononuclear complexes with four-coordinate nickel(II) ions in approximately planar trans- N2S2 coordination environments. In contrast to the parent arenethiol 4a, the sterically more encumbered ligands do not form dinuclear complexes.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.