Abstract
A novel strategy for C–S bond formation is developed. This reaction utilizes a low-cost, air- and moisture-insensitive nickel pre-catalyst to execute a decarbonylative reaction of acid anhydrides, followed by reaction with an odorless and manageable carbon disulfide, to synthesize various thioesters and thioethers. The process accommodated various acid anhydrides and yielded products in good to excellent quantities.
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