Abstract
AbstractA strategy for the Ni-catalyzed decarbonylation of α-oxyacetic acid thioesters is described, providing a new pathway for the synthesis of monosulfide acetals, and further proving that oxygen atoms can stabilize an α-carbocation and promote a decarbonylation reaction. This method has good functional-group compatibility and can tolerate a wide range of electron-withdrawing, electron-neutral, and electron-donating substituents. In addition, this method complements the conventional cross-coupling reactions.
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