Abstract
We offen encounter with cases in which an amorphous or a phases which is not described in a thermal equilibrium diagram appears in an electroplated alloy film and also X-ray diffraction peaks which are not maintained in JCPDS appear in the X-ray diffraction pattern. All of theses are due to the existence of the metastable phase in the plated film. In this paper by investigating the transformation process of two kinds of metastable phases which appear in an electroplated Ni-Sn alloy film as a thermal equilibrium phase by heat treatment, the crystallographic structures of these metastable phases were characterized.
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