Abstract

A thin layer of Ge (1nm) deposited between a 30nm Ni film and a (100)Si substrate was used as a marker for the diffusing species during Ni silicide formation. In situ X-ray diffraction heat treatments with temperatures ranging from 150 to 400°C were performed to show the specific steps of silicide formation. Atom probe tomography (APT) enabled the diffusing species during the Ni deposition and during the formation of δ-Ni2Si and NiSi phases to be determined. APT measurements of the redistribution of Ge during the stress relaxation of δ-Ni2Si and during the formation of NiSi highlighted the mechanisms of stress relaxation and morphological degradation of NiSi.

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