Ni–Co spinel based oxide as new type of additive to glass seal for solid oxide fuel cells

Abstract

Glass seals utilized in Solid Oxide Fuel Cells (SOFCs) can be subject to modification through the incorporation of oxide additives to bolster their mechanical strength. This research focuses on a novel class of additives, specifically protective coating materials designed for alloy interconnects. It is crucial to emphasize that the glass seal interfaces directly with the protective coating, bypassing direct contact with the alloy itself. The efficacy of this approach is exemplified through the utilization of Ni–Co spinel-based oxide, established as an effective protective substance for stainless steel interconnects. The introduction of a minute quantity of Ni–Co oxides does not induce alterations in the glass seal properties, encompassing phase structure, microstructure, thermal expansion coefficient (CTE), and softening behavior. The Ni–Co oxide additive serves to mitigate the glass devitrification tendency, leading to a substantial augmentation in shear strength at the seal-interconnect interface and a marked enhancement in sealing properties. The composite seal, enriched with 3.0 wt% Ni–Co oxide, showcases superior sealing performance, demonstrating exceptional stability throughout a rigorous 1200-h test. The average leakage rate during this test period stands at 0.0024 sccm⋅cm−1. The incorporation of Ni–Co oxide triggers the formation of needle-shaped crystals, playing a pivotal role in averting channel void formation and augmenting the bonding strength between the seal and interconnect. Consequently, this fortifies gas tightness, ensuring the maintenance of outstanding sealing performance over an extended duration.