Abstract
Sixteen-electron Ni(0) complexes bearing trans-stilbene derivative ligands have been shown to display a high degree of stability toward oxidation in the solid state. A structural analysis of a uniq...
Highlights
The use of nickel (Ni) to catalyze organic transformations has gained tremendous momentum as a sustainable alternative to more noble metals.[1]
Catalysis is limited to its combination with strongly nucleophilic ligands, due to the highly coordinating DQ.[10]
The development of a simple, scalable, and modular Ni(0) source which is bench, air, and temperaturestable but retains the levels of reactivity demonstrated by Ni(COD)[2] is still highly desirable
Summary
The Organic Chemistry of Nickel; Academic Press: New demand imbued by the substituents at the para position of the. This fundamental observation permitted the rational design of Ni(4‐tBustb)[3] (6), which proved to be a superior Ni(0) source with remarkable physical properties. Complex 6 has been shown to perform at the same level as. Studies toward studying the origin of such of Nickel; Academic Press: New York, 1975; Vol 2. C. Transition metal-catalyzed alkyl−alkyl bond formation: another dimension in cross-coupling chemistry. F. Recent advances in homogeneous nickel catalysis.
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