Abstract

The title compound has been characterized by means of X- ray crystallography. The cyanato ligand acts as a bridge between the square planar [Ni(3,2,3-tet)] 2+ entities (3,2,3- tet= N,N′-bis(3-aminopropyl)-1,2-ethanediamine), giving an unprecedented chain structure. Crystal data for [{Ni(3,2,3-tet) (μ-NCO)} n ](ClO 4) n : FW=374.47, monoclinic, space group P2 1/ n, a=10.587(2), b=12.395(2), c=11.871(2) Å, β= 92.00(1)°, Z=4, D c=1.597 g cm −3, R=0.038, R w=0.041. The magnetic susceptibility data indicate weak ferromagnetic coupling.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.