NH2-CuO-MCM-41 covalently cross-linked multipurpose membrane for applications in water treatment: Removal of hazardous pollutants from water, water desalination and anti-biofouling performance

Abstract

The current study was planned to fabricate a new set of membranes to target multiple application areas such as desalting, removal of micropollutants and antibiofouling performance. In-situ incorporated copper oxide to MCM-41 (CuO-MCM-41) was synthesized and amine (-NH2) functionalized by reacting with N1-(3-trimethoxy silylpropyl) diethylenetriamine (NTSDETA) yielding NH2–CuO-MCM-41. Different concentrations of NH2–CuO-MCM-41 were covalently cross-linked in polyamide active layer during interfacial polymerization (IP) between N, N′-bis(3-aminopropyl)ethylenediamine and terephthaloyl chloride (TPC) on polysulfone/poly ester terephthalate (PS/PET) support. The membranes were extensively characterized by Water Contact Angle (WCA), Scanning Electron Microscopy (SEM), Fourier Transform Infra-red (FTIR) spectroscopy, Energy Dispersive X-ray (EDX) analysis, Elemental mapping and Powder X-ray Diffraction (PXRD). From among the different versions of X-CuO-MCM-41/PA@PS/PET membranes, the 0.05%-CuO-MCM-41/PA@PS/PET membrane showed best performance in terms of rejecting a variety of salts, micropollutants and antibiofouling. The 0.05%-CuO-MCM-41/PA@PS/PET showed >98% rejection of MgCl2 and 78% rejection of caffeine with a permeate flux of 16 LMH at 25 bar. The 0.1-NH2-CuO-MCM-41inhibited S. aureus growth by 51.7%. Hence, the current strategy of membrane fabrication proved to be highly efficient for multipurpose applications in water treatment.