Abstract
A zinc diphosphonate, (H2G)0.5[Zn3(L)(HL)]·3H2O (G = 4-picolylamine, H4L = 1-hydroxyl-2-(3-pyridyl)ethylidene-1,1-diphosphonic acid) displays a 3D pillared open-framework with ellipsoid-like 12MR channels, bright tunable luminescence and thermally stable up to 250 °C under an air atmosphere.
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