New U–Pb ages and lithochemical attributes of the Ediacaran Rio Doce magmatic arc, Araçuaí confined orogen, southeastern Brazil

Abstract

The Araçuaí orogen of southeastern Brazil, together with its counterpart located in Africa, the West Congo belt, formed through closure of a gulf connected to the Adamastor Ocean by the end of the Ediacaran and beginning of the Cambrian. Convergence of the margins of the gulf led to the development of the Rio Doce magmatic arc between 630 Ma and 580 Ma on a continental basement mostly composed of Rhyacian orthogneisses. The Rio Doce arc mainly consists of tonalite-granodiorite batholiths, generally crowded with mafic to dioritic enclaves, and minor gabbronorite-enderbite-charnockite plutons, suggesting mixing processes involving crustal and mantle sources. We investigate the basement, magma sources and emplacement ages of the Rio Doce arc. Our data suggest the arc comprises three main granitic rock groups: i) Opx-bearing rocks mostly of enderbite to charnockite composition; ii) enclave-rich tonalite-granodiorite (ETG); and iii) enclave-poor granite-granodiorite with minor tonalite (GT). The Opx-bearing rocks are magnesian, calc-alkalic to alkali-calcic and metaluminous. Together, the ETG and GT rock groups range in composition from tonalite to granite, are metaluminous to slightly peraluminous, show a predominantly medium- to high-K, expanded calc-alkaline signature, and other geochemical and isotopic attributes typical of a pre-collisional volcanic arc formed on a continental margin setting. Mineralogical, chemical, and geochronological data suggest the involvement of HT-melting of granulitic (H2O-depleted) sources of Rhyacian age for the generation of Opx-bearing granitic rocks, additionally to magma mixing and fractional crystallization processes. In conclusion, the studied rock groups of the Rio Doce arc were likely formed by interactions of mantle and crustal processes, in an active continental margin setting. These processes involved ascent of mantle magmas that induced partial melting on the continental basement represented by the Rhyacian gneisses.