New-type low-cost cathode materials for Li-ion batteries: Mikasaite-type Fe2(SO4)3

Abstract

In the present work, a new-type low-cost lithium ion battery cathode material, the Mikasaite-type iron sulfate, has been studied. It can be prepared by heating the water-containing iron sulfate raw chemicals in air atmosphere. The experimental results have shown that the oxidation and the reduction peaks are 3.92 and 3.37 V in the cyclic voltammogram, respectively, when the scanning rate is 0.05 mV s−1. The galvanostatic measurements have explored that the voltage plateau during charging is slightly less than 3.70 V and the discharge voltage plateau is 3.40 V for the first cycle and 3.50 V for the following cycles at 0.1 C rate. The discharge capacity in the first cycle can reach 116 mAh g−1, about 87 % of the theoretical capacity (134 mAh g−1). It is believed that the product in the fully discharged state is Li2Fe2(SO4)3. However, the insertion reaction is reversible only for the second lithium ion. During cycling, the reversible capacity remains about 60 mAh g−1. Further capacity fade is not found in the 20 discharge–charge cycles. The electrochemical impedance measurements have shown that there are two compressed semicircles in the Nyquist plots and a Warburg impedance in the low-frequency domain. The high-frequency semicircle is related with the electrode’s structural factor and the intermediate-frequency semicircle corresponds to the charge-transfer process.