New Trends and Perspectives in Production of 1,2-Propanediol

Abstract

The production of 1,2-propanediol is a significant challenge for the chemical industry due to the increasing demand for this versatile product and the pro-ecological regulatory actions. The traditional method of producing this compound through the hydrolysis of petroleum-derived 1,2-epoxypropane (propylene oxide) is energy intensive, and sustainable routes based on renewable raw materials are becoming more attractive. This perspective presents the current state of scientific and patent literature on the production of 1,2-propanediol and the implementation of new technologies by leading companies. This perspective also discusses alternative pathways, including glycerol hydrogenolysis and biotechnological methods, highlighting their potential to reduce energy consumption and lower the carbon footprint of the process. The focus is on modern methods, including chromium-free catalytic systems for glycerol hydrogenolysis, in situ hydrogen generation, and multifunctional catalysts for saccharides hydrolysis and hydrogenolysis. Biobased 1,2-propanediol produced from renewable alternative raw materials has great potential to replace traditional petroleum-derived 1,2-propanediol with substantial environmental and economic benefits.