Abstract
A novel coordination geometry of phosphorus is achieved in a simple way by the reaction of the (η2-tert-butylphosphaalkyne)titanocene 1 with tetraethyldiborane [Eq. (a)]. The resulting dinuclear complex 2 contains a planar tricoordinate phosphorus atom whose lone pair of electrons is not involved in bonding.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Angewandte Chemie International Edition in English
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.