Abstract

Three isostructural 2-D square grid coordination polymers [Ln 2(NDC) 3(phen) 2(H 2O) 2] (Ln = La ( 1), Eu ( 2), Ho ( 3), NDC = 1,4-naphthalenedicarboxylate, phen = 1,10-phenanthroline) were synthesized by hydrothermal reactions of lanthanide chloride with 1,4-naphthalenedicarboxylic acid and phen. The 2-D coordination polymers were assembled into 3-D networks via O–H ⋯ O hydrogen bond. The photophysical property, magnetic property and thermal stability of complex 2 were investigated.

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