Abstract
The metal-promoted reactions between 2,6-diacetylpyridine and 3,6-dioxaoctane-1,8-diamine, 4,9-dioxadodecane-1,12-diamine or 4,7,10-trioxatridecane-1,13-diamine in the presence of yttrium(III) and lanthanide(III) ions acting as template agents afford new supramolecular dinuclear complexes of podate type with terminal acetylpyridyl groups and N 4O 4 and N 4O 5 set of donor atoms as a result of [2+1] Schiff base condensation. The complexes were characterized by spectral data (IR, 1H NMR, FAB-MS) and elemental analysis.
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