New structural motifs in Mn cluster chemistry from the ketone/gem-diol and bis(gem-diol) forms of 2,6-di-(2-pyridylcarbonyl)pyridine: {MnII4MnIII2} and {MnII4MnIII6} complexes

Dimosthenis P Giannopoulos,Rafael Ballesteros-Garrido,Theocharis C Stamatatos,Albert Escuer,Belén Abarca,Rafael Ballesteros,Luís Cunha-Silva

doi:10.1039/c6ra22953k

New structural motifs in Mn cluster chemistry from the ketone/gem-diol and bis(gem-diol) forms of 2,6-di-(2-pyridylcarbonyl)pyridine: {MnII4MnIII2} and {MnII4MnIII6} complexes

Dimosthenis P Giannopoulos, Rafael Ballesteros-Garrido + Show 5 more

https://doi.org/10.1039/c6ra22953k

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Journal: RSC Advances	Publication Date: Jan 1, 2016
Citations: 6

Affiliation: Toronto General Hospital, Brock University, University of Valencia, Hospital de Sant Pau, University of Barcelona, University of Porto

#Presence Of MnCl2 #Magnetic Susceptibility Studies + Show 8 more

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Abstract

The ketone/gem-diol (L1H2) and bis(gem-diol) (L2H4) forms of the ligand 2,6-di-(2-pyridylcarbonyl)pyridine in Mn cluster chemistry have afforded the new complexes [MnII4MnIII2(N3)6Cl4(L1)2(DMF)4] and [MnII4MnIII6O2(N3)12(L1)2(L2H)2(DMF)6].

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