New Structural Motifs in Metallaborane Chemistry. Synthesis, Characterization, and Solid-State Structures of (Cp*W)3(μ-H)B8H8, (Cp*W)2B7H9, and (Cp*Re)2B7H7 (Cp* = η-C5Me5)

Andrew S Weller,Thomas P Fehlner,Mayou Shang

doi:10.1021/om980814c

New Structural Motifs in Metallaborane Chemistry. Synthesis, Characterization, and Solid-State Structures of (CpW)3(μ-H)B8H8, (CpW)2B7H9, and (CpRe)2B7H7 (Cp = η-C5Me5)

Andrew S Weller, Thomas P Fehlner + Show 1 more

https://doi.org/10.1021/om980814c

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Journal: Organometallics	Publication Date: Feb 5, 1999
Citations: 43

Affiliation: University of Notre Dame

#Skeletal Electron Pair #Hydrogen Loss + Show 3 more

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Abstract

Hydrogen loss from the 7 skeletal electron pair (sep) nido 2-Cp*H3WB4H8, 1 (Cp* = η-C5Me5), the metal analogue of pentaborane (9), has been examined as a potential source of unsaturated, reactive s...

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