Abstract
AbstractThe luminescent complex [4‐(3‐hydroxypropyl)‐4′‐methyl‐2,2′‐bipyridine]‐bis(2,2′‐bipyridine)‐ruthenium(II)‐bis(hexafluoroantimonate) and its methacrylate derivative were successfully synthesized and fully characterized by two‐dimensional 1H and 13C{1H} NMR techniques [correlation spectroscopy (COSY) and heteronuclear multiple‐quantum coherence experiment (HMQC)], as well as matrix‐assisted laser desorption ionization time‐of‐flight mass spectrometry. The respective labeled methyl methacrylate‐ruthenium(polypyridyl) copolymers were obtained by free‐radical copolymerization with methyl methacrylate and were characterized utilizing NMR, IR, and UV–visible spectroscopy and gel permeation chromatography. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3954–3964, 2003
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