Abstract
Abstract New styryl ruthenium-molybdenum and -tungsten complexes Cp(CO)3M-Ru (trans-styryl)(CO)(PPh3)2 [M = Mo (2), W (3)] have been prepared by the metathetical reactions of Ru(trans-styryl)Cl(CO)(PPh3)2 with Na[MCp(CO)3]. The reactions of 2 with CO and with PMe3 give Cp(CO)3Mo-Ru(trans-styryl)(CO)2(PPh3)2 (4) and Cp(CO)3Mo-Ru(trans-styryl)(CO)(PMe3)2 (5), respectively. The complexes of 2, 3, 4, and 5 have been characterized by IR, 1H NMR, 31P{1H} NMR spectroscopy, and elemental analysis.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
