New routes for the synthesis of chloro(diethylenetriamine) platinum(II) chloride and chloro(2,2′ : 6′,2″-terpyridine) platinum(II) chloride dihydrate

Giuliano Annibale,Matilde Brandolisio,Bruno Pitteri

doi:10.1016/0277-5387(94)00408-7

New routes for the synthesis of chloro(diethylenetriamine) platinum(II) chloride and chloro(2,2′ : 6′,2″-terpyridine) platinum(II) chloride dihydrate

Giuliano Annibale, Matilde Brandolisio + Show 1 more

https://doi.org/10.1016/0277-5387(94)00408-7

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Journal: Polyhedron	Publication Date: Feb 1, 1995
Citations: 129

Affiliation: Ca' Foscari University of Venice

#Interaction Of Cis #2H 2O + Show 5 more

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Abstract

[Pt(dien)Cl]Cl (dien = diethylenetriamine) has been obtained in high yield ( > 90%) by interaction of cis-[Pt(dmso) 2Cl 2] (dmso = dimethylsulfoxide) with the triamine in methanol. The same method, when applied to 2,2′ : 6′,2″-terpyridine (terpy), gave a mixture of [Pt(terpy)Cl][Pt(dmso)Cl 3] and [Pt(terpy)Cl]Cl·2H 2O. The latter complex has been obtained in nearly quantitative yield by interaction of equimolar amounts of [Pt(COD)Cl 2] (COD = 1,5-cyclooctadiene) and terpy in water.

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