Abstract
A new route to 1,1-difluoro-5-methylquasisilatrane (N→Si) F2Si(OCH2CH2)2NMe is elaborated: the reaction of chlorinated methyltrifluorosilanes F3SiCH3−nCln (n = 1–3) as well as trifluoro(3-chloropropyl) silane and trifluoro(propenyl)silane with N-methyl-bis(2-hydroxyethyl)amine. The reactivity of the silanes F3SiCH3−nCln increases with the number of chlorine atoms, that is, with the electronegativity of the CH3−nCln group.
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