Abstract
AbstractNo radicals are formed in bis(mercaptopropionate)‐diene‐mixtures, as shown by means of ESR spectroscopic investigation. Radicals are produced spontaneously only in the presence of triethylene glycol dithiol. The hydrogen‐bonded structure of the dithiopropionates is obviously responsible for the inhibition of the charge transfer interaction with the diene compounds and prevents subsequent radical formation. The 13C NMR spectra confirm the anti‐Markownikow structure of the polymers formed with diallyl succinate and diallyl terephthalate.
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