New Preparation Method of Low‐Temperature‐Sinterable Perovskite 0.9Pb(Mg1/3Nb2/3)O3‐0.1PbTiO3 Powder and Its Dielectric Properties

Abstract

A relaxor ferroelectric material, 0.9Pb(Mg1/3Nb2/3)O3‐0.1PbTiO3 (0.9PMN‐0.1PT) with a pyrochlore‐free phase, was prepared by using one‐step calcination in the present study. The 0.9PMN‐0.1PT powder with the pure perovskite phase was prepared successfully from a mixture of the PMN precursor and the crystalline PT by heating for 2 h at temperatures greaterthan equal to750°C. The PMN precursor was synthesized by adding an aqueous Mg(NO3)2 solution, rather than MgO, to the alcoholic slurry of PbO and Nb2O5. The 0.9PMN‐0.1PT powder sintered to >96% relative density via heat treatment for 2 h at temperatures of 900°‐1200°C. The highest room‐temperature dielectric constant (epsilonrt) was 24700 at 1 kHz for the samples that were sintered at 1100°C; however, the samples that were sintered at 900°C still had epsilonrt values of 22600 at 1 kHz.