Abstract

Potassium hydrogen fluoride KHF2 is tetragonal at room temperature: a=5.667(1) Å, c=6.795(1) Å, d=2.38, Z=4, space group I4/mcm (No. 140). It gives a polymorphic transition at 196 °C to a cubic form: a=6.435(1) Å, Z=4, space group Fm3m, melts at 239 °C, and then dissociates into gaseous HF and solid KF.

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