Abstract
A method for the preparation of new representatives of polynitrogen hyperbranched polymers of heterocyclic series was developed involving polymerization of monomeric 2,4-diazido-6-propynyloxy-1,3,5-triazine by 1,3-dipolar cycloaddition. Kinetics of polymerization of diazidoacetylene monomer was compared with the kinetic data of polymerization of its closest analog, 2-azido-4,6-bis(propynyloxy)-1,3,5-triazine monomer. Properties of hyperbranched poly(1,2,3-triazole-1,3,5-triazine)s with terminal azide groups and terminal triple bonds were compared, as well.
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