Abstract
Single crystal of a new polymorph of 1,3,5-triazine-2,4,6-triaminehexaacetic acid has been growth and characterized. The structure of the title polymorph crystallized in the monoclinic space group C2/c with the unit cell parameters a = 20.443(4) A, b = 10.5104(14) A, c = 9.8022(11) A, β = 118.212(6)°, V = 1855.9(5) A3, Z = 4, R = 0.112, Rw = 0.273 and S = 1.038. The principal feature of the new polymorph is characterized by a bundle of molecular columns each of which is built up of molecular units stacked along c in the offset face-to-face manner. Significance of hydrogen bonding interactions in regulating the assembly of molecules in the structure is then demonstrated. Detailed differences in molecular conformation, type and pattern of hydrogen bonding interactions are discussed and distinguished from the previous polymorph. The vibrational and electronic spectroscopic studies are included. Microwave-assisted crystal growth and structure of 1,3,5-triazine-2,4,6-triaminehexaacetic acid new polymorph.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
