Abstract
When obtaining estimates that characterize the level of fire safety of the hydrogen storage and supply system, there is an error due to the subjective nature of its occurrence. It is noted that it is possible to weaken the influence of the subjective nature on these estimates by using the probabilistic characteristics of failure of the main elements of the hydrogen storage and supply system. Such basic elements include a gas generator. It is shown that the diffusion processes between the hydroreactive sample and the liquid - water are accompanied by the appearance of gas bubbles located on the reacting surface. This process - chemical boiling is characterized by internal characteristics. Internal characteristics were obtained experimentally for hydroreactive samples based on sodium aluminum hydride, which are approximated by polynomials of the fourth order and represent the dependence of the diameter of gas bubbles and the generation frequency on the diameter of the reacting surface. It is noted that the characteristics of the gas generator depend on the orientation of the reacting surfaces of the hydroreactive sample. The growth rate of basic bubbles practically does not depend on the diameter of the reacting surface, and the size of this surface for the vertical arrangement of the reacting surface is several percent larger than for its horizontal arrangement. The most unfavorable mode of gas generation is the case when the reactive surface of the hydro-reactive sample is oriented downwards. It is shown that increasing the reliability of the gas generator of the hydrogen storage and supply system is possible due to the implementation of a hydroreactive sample with a polylike one - a passive method and due to the formation of hydrodynamic forces acting on gas bubbles - an active method. These recommendations are embodied on the example of a hydrogen storage and supply system with vibrational movement of a hydroreactive sample, which is made in the form of a set of identical long cylinders assembled in a mesh cassette. Keywords: water saving and supply system, gas generator, fire safety, reliability.
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