Abstract
Seven new organotin (IV) carboxylates have been synthesized by the reactions of 6-chloro-3-pyridineacetic acid with triorganotin chloride and diorganotin dichloride. All the complexes were characterized by elemental analysis, IR, 1H NMR, 13C NMR, 119Sn NMR and X-ray crystallography. The structural analyses show that all the complexes present various structures, including monomer, drum, 1D polymers and ladders. It is worth noting that complex 1 is a novel 1D spring-like helical chain containing guest solvent molecules.
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