Abstract
Mixed oxides on the basis of bismuth niobate and lithium molybdate are perspective materials for application in fuel cells, gas separation membranes, cryogenic scintillating bolometers, etc. In the research, compounds Bi3R0.8Nb0.2O6.2 (R = Dy, Er) were synthesized and single crystals Li2MoO4, Li2W1−xMoxO4 were grown. The thermodynamic properties (the standard formation enthalpies, heat capacities, lattice enthalpies) were measured by solution and differential scanning calorimetry. As results, it was shown that there is linear dependence of lattice enthalpies for Li2W1−xMoxO4 from tolerance factor, there is no phase transition for Li2W0.9Mo0.1O4 up to 900 K. There is phase transition for Bi3Dy0.8Nb0.2O6.2 above 560 K.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
