Abstract

Tris(trimethylsilyl) antimonite, (Me3SiO)3Sb was for the first time prepared by the reaction of trimethylsilanol with triethyl antimonite in 67% yield [1]. But the strong tendency of trimethylsilanol to take part in anhydrocondensation resulting in the formation of hexamethyldisiloxane decreased the preparative value of this method. The attempts to prepare tris (trimethylsilyl) antimonite by the reaction of sodium trimethylsilanolate with the antimony trichloride [2] or trimethylsilanol with the antimony triacetate [3] failed. Later tris(trihydrocarbylsilyl) antimonites attracted the attention of many researchers [4–6] and were used as precursors of the antimony silicate glass for coatings in microelectronics [7].

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.