Abstract
A new method for calculating the pairwise effective potential on arbitrary shells of the binary disordered solid solutions is proposed with account for the linear size effect. The method is based on the fitting of the order–disorder temperature calculated by the model potential method to its known experimental value. In disordered Cu $${}_{3}$$ Au alloy, the pairwise effective potential is calculated and the short-range order parameters on the first fourteen shells are estimated using the Krivoglaz–Clapp–Moss method. A satisfactory coincidence with the experimental data is obtained.
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