Abstract
Abstract The synthesis and characterization of Mn(II), Cu(II), Co(II), Ni(II), Pb(II) and UO2 (VI) complexes of the new ligand 1-N-(6-nitrobenzimidazole-1-carbonylmethyl)-4-(α-naphthyl)-3-thiosemicarbazide (NBNMS) is reported. Infrared spectral data show that NBNMS behaves as a tetradentate ligand involving the carbonyl and thiocarbonyl groups in conjunction with the adjacent nitrogen atoms (C = N groups). Each ligand bridges to two metal centers. This result in polymers that grow through consecutive ligand-metal linkages for all but UO2 (VI). In contrast, NBNMS acts as a monobasic tridentate ligand with UO2(VI).
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