Abstract

New lead-fluorozirconate glasses in the system ZrF4–PbF2–BiF3 were investigated. The stabilizing effect of BiF3 on the binary system ZrF4–PbF2 glasses was established. A complete investigation of this system allowed us to obtain samples of up to 3mm in thickness. Its further optimization was achieved by introduction of other fluorides resulting in increased resistance to devitrification. Thermal and optical data are reported.

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