Abstract
Three-dimensional step polymerization of ABB/ and В3 monomers (ABB/+В3) was described using the new structural-kinetic model. Polymerization process was simulated with the variation of reactivity of B groups in the ABB/ and B3 monomers during the process (substitution effect). Polymerization simulation with substitution effect represents the most general case of three-dimensional step polymerization ABB/+В3.
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