New insights on the preparation of amine covalent organic polymer and its adsorption properties

Abstract

Dye pollution is becoming increasingly severe. This study used the Schiff base reaction to synthesize a polyaromatic ring covalent organic polymer material with amide bonds and high electronegativity named SLEL-9 to adsorb Methylene Blue (MB) and Rhodamine B (RhB). SLEL-9 was characterized by Fourier transform infra-red spectra, X-ray photoelectron spectra, Brunauer-Emmett-Teller (BET), zeta potential analysis, and other techniques. It was found that SLEL-9 material contains C–C, CN, C–N, and CO. SLEL-9 had a zeta potential of about −45 mV under neutral conditions, which proved that the material had been synthesized successfully. The BET and Langmuir surface areas of SLEL-9 were 35.187 m2 g−1 and 56.419 m2 g−1, respectively. The adsorptions of SLEL-9 on low concentration (10 mg L−1) Methylene Blue and Rhodamine B reached equilibrium within 48 h. The results showed that SLEL-9's adsorption of dye molecules are more consistent with pseudo-second-order kinetic and Langmuir isotherm model. The adsorption experiments showed that the adsorption process is a spontaneous endothermic reaction, mainly chemisorption. The maximum adsorption capacity of SLEL-9 for MB and RhB were 132.45 mg g−1 and 101.94 mg g−1. In addition, this study investigated to determine the optimal reaction parameters. The primary mechanisms of SLEL-9 adsorption of two dyes are n→π* interaction, π-π EDA interaction and electrostatic attraction. Selective adsorb ability experiment results showed that SLEL-9 could selectively adsorb MB and RhB to a certain extent. Finally, it was found that SLEL-9 can maintain over 70% adsorption capacity after five reuses and can maintain stability after soaking in different pH water and organic solvents for 120 h. SLEL-9 proved to be a promising organic covalent polymer adsorption material for the removal of Methylene Blue and Rhodamine B in water.