New insights into the pre-ignition behavior of methane behind reflected shock waves

Abstract

Pre-ignition is an undesired combustion event known to restrict kinetic modeling validation. Previous methane oxidation studies reported premature ignition as part of ignition delay time measurements in shock tubes. In this context, the effect on the pre-ignition propensity and auto-ignition behavior of stoichiometric methane mixtures at different dilution levels of hbox {N}_2, Ar, He, and hbox {CO}_2 was studied at 10 bar and 25 bar and temperatures between 1080 K and 1350 K. In addition to conventional sidewall pressure and endwall light emission measurements, a high-speed imaging setup was utilized to visualize the ignition process. Relevant physicochemical parameters to describe and predict the pre-ignition phenomenon were used. The results suggest that dilution levels up to 80% of bath gas are not successful in mitigating early ignition occurrence and its effects at moderate pressures. Replacing hbox {N}_2 by He was found to suppress early ignition at 10 bar, attributed to an enhanced dissipation of temperature inhomogeneities in the test gas section. The present findings demonstrate that hbox {CO}_2 has potential for pre-ignition heat release mitigation, while Ar was confirmed to promote premature ignition. To the best of our knowledge, we present the first detailed study on pre-ignition mitigation for methane mixtures in shock tubes, where further insights into its ignition non-idealities are given.