New Insights into the Dissolution Kinetics of Alite Powder and the Effects of Organic Toughening Materials.

Abstract

Alite dissolution plays a crucial role in cement hydration. However, quantitative investigations into alite powder dissolution are limited, especially regarding the influence of chemical admixtures. This study investigates the impact of particle size, temperature, saturation level, and mixing speed on alite powder dissolution rate, considering the real-time evolution of specific surface area during the alite powder dissolution process. Furthermore, the study delves into the influence of two organic toughening agents, chitosan oligosaccharide (COS) and anionic/non-ionic polyester-based polyurethane (PU), on the kinetics of alite powder dissolution. The results demonstrate a specific-surface-area change formula during alite powder dissolution: SS0=0.348e1-m/m0/0.085+0.651. Notably, the temperature and saturation level significantly affect dissolution rates, whereas the effect of particle size is more complicated. COS shows dosage-dependent effects on alite dissolution, acting through both its acidic nature and surface coverage. On the other hand, PU inhibits alite dissolution by blocking the active sites of alite through electrostatic adsorption, which is particularly evident at high temperatures.