New hydrophilic polymeric resin based on 4-vinylpyridine–divinylbenzene for solid-phase extraction of polar compounds from water

Abstract

A 4-vinylpyridine–divinylbenzene (VP–DVB) resin was synthesized to be used for on-line solid-phase extraction process and it was tested for a group of polar compounds. The high specific surface area and the nitrogen content of the VP–DVB sorbent increased the interactions with the polar analytes in the preconcentration process. The sorbent enabled 100 ml of water to be concentrated with recoveries higher than 70% for several polar compounds (including phenol) except for oxamyl (55%) and methomyl (43%). The method was used to analyse water samples by liquid chromatography and UV detection. Linearity was good and detection limits were 0.1–0.2 μg l −1 for all compounds. Several tap and river water and waste water treatment plant samples were analyzed; phenol and (4-chloro-2-methyl-phenoxy)acetic acid (MCPA) were tentatively determined in some samples.