Abstract

Several new oxygen-M-graphite compounds (where M is Rb or Cs) with general formula MC4nOx (n = 1, 2, 0.1 < x < 0.6), were obtained. X-ray diffraction study has shown that these compounds contain two-layered alkali metal packing between graphitic sheets, di for Rb compounds being 8.82–9.20 A, for CsGICs: 9.60 A. It was shown that in some cases this double-layered stacking can be transformed to the dense monolayered one under high pressure conditions.

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