New GC quartz-lined aluminum capillary columns coated with graphitized carbon black modified by liquid phases

Abstract

Fused silica is by far the best material for most kinds of GC capillary columns but in some particular conditions, when a drastic acidic or alkaline treatment is required, this material and especially the polyimide protector layer do not possess high chemical resistance and could easily break down. In order to overcome this disadvantage, in this paper, we present a new type of column — a quartz-lined aluminum capillary coated with graphitized carbon black modified by liquid phases by using a new coating procedure. With the above material a capillary column for amine analysis, and another for the analysis of VOCs and oil products are obtained. Some characteristic applications of both columns are reported.