Abstract
A new color-tunable Eu2+-doped sodium aluminium silicate, Na2−x−yAl2−xSixO4:yEu2+ (0 ≤ x ≤ 1), phosphor system was investigated as a novel candidate for phosphor-converted white light-emitting diode (LED) applications and successfully synthesized by wet chemical methods based on the hydrolysis of tetraethyl orthosilicate (TEOS). Different crystal structures and emission spectra were obtained by varying the ratio of Al to Si in the phosphor Na2−xAl2−xSixO4 with x value ranging from 0.25 to 0.55. The Na2−x−yAl2−xSixO4:yEu2+ phosphor system emitted a maximum intensity at 470–600 nm when using a 395 nm excitation wavelength, and the emission was strongly affected by the crystal structures determined by the x value. Substitution of Eu2+ affected the center wavelength and emission intensity due to changes in the crystal-field effect, which was strongly dependent on the crystal structure. The LED device exhibited an excellent color-rendering index Ra of 93 at a correlated color temperature of 4258 K with CIE color coordinates of (0.3629, 0.3427) under a 20 mA forward-bias current. Based on these results, we are currently evaluating the potential application of Na2−x−yAl2−xSixO4:yEu2+ as a white-emitting UV-convertible phosphor.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
