New free-radical halogenations of alkanes, catalysed by N-hydroxyphthalimide. Polar and enthalpic effects on the chemo- and regioselectivity

Francesco Minisci,Ombretta Porta,Francesco Recupero,Cristian Gambarotti,Roberto Paganelli,Gian Franco Pedulli,Francesca Fontana

doi:10.1016/j.tetlet.2003.12.130

New free-radical halogenations of alkanes, catalysed by N-hydroxyphthalimide. Polar and enthalpic effects on the chemo- and regioselectivity

Francesco Minisci, Ombretta Porta + Show 5 more

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https://doi.org/10.1016/j.tetlet.2003.12.130

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Journal: Tetrahedron Letters	Publication Date: Jan 20, 2004
Citations: 23

Affiliation: Politecnico di Milano, University of Bologna, University of Bergamo

#N-oxyl Radical #Importance Of Polar Effects + Show 4 more

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Abstract

Reactions of alkanes with different halogenating systems are compared in order to explore the reactivity of phthalimido- N-oxyl radical in hydrogen abstraction; the importance of polar effects is emphasised.

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