Abstract
A series of novel random copolymers of poly(propylene 1,4-cyclohexanedicarboxylate) (PPCE) containing neo - pentyl glycol sub-unit (P(PCExNCEy)) were synthesized and characterized in terms of molecular and solid-state properties. In addition, biodegradability studies in compost have been conducted. The copolymers displayed a high and similar thermal stability with respect to PPCE. At room temperature, all the copoly- mers appeared as semicrystalline materials: the main effect of copolymerization was a lowering of crystallinity degree (!c) and a decrease of the melting temperature compared to the parent homopolymer. In particular, Wide Angle X-Ray diffrac- tion (WAXD) measurements indicated that P(PCExNCEy) copolymers are characterized by cocrystallization, PNCE co- units cocrystallizing in PPCE crystalline phase. Final properties and biodegradation rate of the materials under study were strictly dependent on copolymer composition and !c. As a matter of fact, the elastic modulus and the elongation at break decreased and increased, respectively, as neopentyl glycol cyclohexanedicarboxylate (NCE) unit content was increased. The presence of a rigid-amorphous phase was evidenced by means of Dynamic Mechanical Thermal Analysis (DMTA) analysis in all the samples under investigation. Lastly, the biodegradation rate of P(PCExNCEy) copolymers was found to slightly increase with the increasing of NCE molar content.
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