Abstract

N,N′-Dimethylcyclodisilazanes -SiMeRNMeSiMeR′NMe- , (R = R′= Me, Vi, or Et and R = Me, R′= Vi, Et, or Ph where Vi = vinyl) have been prepared in good yield by cyclization of bis(methylamino)silanes with chlorosilanes. 1H, 13C, 29Si and 15N NMR spectra have been assigned. The four-membered cyclic structure of the compounds have been confirmed by mass spectrometry and IR absorption measurements.

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