Abstract
AbstractThe synthesis of some poly(bisphenol‐A)carbonates (PCs) containing hydrophilic porphyrin units as end groups, by thermal treatment of commercial PC and 5,10,15‐tri{p[ω‐methoxy‐poly(oxyethylene)]phenyl}20(p‐hydroxy phenyl)porphyrin (I) blends, is reported. A suitable choice of reaction temperature, molar composition and reaction time, allowing the extent of the outer‐inner transesterification reactions, leads to a gradual insertion of porphyrin units in the polymer chains. The composition of the obtained materials was inferred by GPC and MALDI‐TOF mass spectrometric analysis.
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